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A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

Cunyao Li, Wenlong Wang, Li Yan, Yunjie Ding

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 113-123 doi: 10.1007/s11705-017-1672-9

Abstract: There are two strategies to afford such a catalyst for the hydrofromylation: immobilized catalysts onsolid support and porous organic ligand (POL)-supported catalysts.linear regioselectivity could be achieved through the copolymerization of vinyl functionalized bidentate ligand(vinyl biphephos) and monodentate ligand (3vPPh ) into the catalyst framework.The newly-emerging POL-supported catalysts have great perspectives in the industrial hydroformylation

Keywords: hydroformylation     porous organic ligand (POL)-supported catalysts     heterogeneous catalysis     high stability     immobilization catalysts    

Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 9,   Pages 1289-1300 doi: 10.1007/s11705-023-2299-7

Abstract: Therefore, the design of efficient, stable and long-lifetime catalysts is a worthwhile research goal.large surface area could promote the transport of electrons between NCM and Pd, thereby endowing NCM supportedThe NCM supported Pd catalyst was employed in the degradation of some representative dyes and the chemoselective

Keywords: biowaste chitin     nanofibrous     palladium     nano-catalyst     catalysis    

Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 939-949 doi: 10.1007/s11705-022-2152-4

Abstract: microfluidic strategy to controllably fabricate uniform polymeric microparticles containing hierarchical porousof organic contaminants.The obtained microparticles possess interconnected hierarchical porous structures decorated with highlyaccessible Fe-based metal-organic framework nanorods for enhanced degradation of organic contaminantsThis work provides a simple and general strategy to flexibly combine hierarchical porous structures and

Keywords: metal-organic framework     polymer microparticle     nanocatalyst     decontamination     organic contaminant    

Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 1962-1972 doi: 10.1007/s11705-023-2359-z

Abstract: Despite the commercial application of the high-temperature water gas shift, novel catalysts characterizedIn this work, we propose bimetallic iron-copper catalysts supported on ceria, characterized by low active

Keywords: water gas shift     iron     copper     bimetallic catalysts     ceria     hydrogen    

Catalytic combustion of volatile organic compounds using perovskite oxides catalysts—a review

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1649-1676 doi: 10.1007/s11705-023-2324-x

Abstract: With the rapid development of industry, volatile organic compounds (VOCs) are gaining attention as acombustion is the most popular technology used for the removal of VOCs as it can be adapted to different organicNext, the characteristics and catalytic performance of perovskite oxides as catalysts for VOC removalThe challenges and the prospects regarding the design of perovskite oxides catalysts for the catalyticThis review provides a reference base for improving the performance of perovskite catalysts to treat

Keywords: perovskite oxides     volatile organic compounds     catalytic combustion     reaction mechanism    

Conversion of CO into CO by high active and stable PdNi nanoparticles supported on a metal-organic framework

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1139-1148 doi: 10.1007/s11705-021-2111-5

Abstract: The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showedused for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supportedComparison of the catalysts synthesized by MIL-101(Cr) and MIL-101-NH2(Cr) as the supports

Keywords: CO oxidation     heterogeneous catalysis     metal-organic framework     NH2 functional group     PdNi    

Crystalline porous materials: from zeolites to metal-organic frameworks (MOFs)

Zaiku Xie, Bao-Lian Su

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 123-126 doi: 10.1007/s11705-020-1921-1

Electrochemical sensor investigation of carbon-supported PdCoAg multimetal catalysts using sugar-containing

Firat Salman, Hilal C. Kazici, Hilal Kivrak

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 4,   Pages 629-638 doi: 10.1007/s11705-019-1840-1

Abstract: Novel PdCoAg/C nanostructures were successfully synthesized by the polyol method in order to develop electrocatalysts, related to the glucose sensor performance of the high glycemic index in beverages. The characterization of this novel PdCoAg/C electrocatalyst was performed by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and high-resolution transmission electron microscopy equipped with energy dispersive X-ray. The characterization results revealed that electronic state of the PdCoAg/C electrocatalyst was modified by the addition of the third metal. The electrochemical performances of the sensor were investigated by cyclic voltammetry and differential pulse voltammetry. The prepared enzyme-free sensor exhibited excellent catalytic activity against glucose with a wide detection range (0.005 to 0.35 mmol∙L ), low limit of detection (0.003 mmol∙L ), high sensitivity (4156.34 µA∙mmol ∙L∙cm ), and long-term stability (10 days) because of the synergistic effect between the ternary metals. The glucose contents of several energy drinks, fruit juices, and carbonated beverages were analyzed using the novel PdCoAg/NGCE/C sensor system. These results indicate the feasibility for applications in the foods industry.

Keywords: non-enzymatic     glucose detection     ternary metals     glycemic index     beverages    

Synthesis of porous carbon from orange peel waste for effective volatile organic compounds adsorption

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 7,   Pages 942-953 doi: 10.1007/s11705-022-2264-x

Abstract: Volatile organic compounds have posed a serious threat to the environment and human health, which requireIn recent years, the preparation of porous carbon from biomass waste for volatile organic compounds adsorptionIn this study, porous carbon was synthesized from orange peel by urea-assisted hydrothermal carbonizationrole of typical components (cellulose, hemicellulose, and lignin) in pore development and volatile organicbetter porosity for efficient volatile organic compounds adsorption.

Keywords: biomass waste     porous carbon     feedstock composition     urea-assisted hydrothermal carbonization     toluene    

Optimized porous clay heterostructure for removal of acetaldehyde and toluene from indoor air

Pu ZHAO,Lizhong ZHU

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 2,   Pages 219-228 doi: 10.1007/s11783-014-0760-z

Abstract: Adsorption is the most widely used technology for the removal of indoor volatile organic compounds (VOCsIn this study, a series of new porous clay heterostructure (PCH) adsorbents with various ratios of micropores

Keywords: porous clay heterostructure     volatile organic compounds     adsorption     adsorbent     indoor air    

Computational design of heterogeneous catalysts and gas separation materials for advanced chemical processing

Huaiwei Shi, Teng Zhou

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 1,   Pages 49-59 doi: 10.1007/s11705-020-1959-0

Abstract: Functional materials are widely used in chemical industry in order to reduce the process cost while simultaneously increase the product quality. Considering their significant effects, systematic methods for the optimal selection and design of materials are essential. The conventional synthesis-and-test method for materials development is inefficient and costly. Additionally, the performance of the resulting materials is usually limited by the designer’s expertise. During the past few decades, computational methods have been significantly developed and they now become a very important tool for the optimal design of functional materials for various chemical processes. This article selectively focuses on two important process functional materials, namely heterogeneous catalyst and gas separation agent. Theoretical methods and representative works for computational screening and design of these materials are reviewed.

Keywords: heterogeneous catalyst     gas separation     solvent     porous adsorbent     material screening and design    

Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang, Zongbi Bao, Huabin Xing, Qilong Ren

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 24-31 doi: 10.1007/s11705-017-1669-4

Abstract: We have successfully prepared a series of Pd-Ni/TiO catalysts by a one-step impregnation-reduction methodAmong these catalysts with different compositions of Ni and Pd, the one with the Ni:Pd ratio of 2.95

Keywords: Pd-Ni bimetallic nanoparticles     nanocatalysis     Suzuki-Miyaura reaction     titanium oxide    

Tuning of the active phase structure and hydrofining performance of alumina-supported tri-metallic WMoNicatalysts via phosphorus incorporation

Shufeng Shan, Haiyan Liu, Gang Shi, Xiaojun Bao

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 59-69 doi: 10.1007/s11705-017-1686-3

Abstract: The effects of phosphorus on the structure and hydrofining performance of tri-metallic WMoNi/Al O catalysts

Keywords: fluid catalytic cracking diesel     hydrofining performance     WMoNiP/Al2O3     synergetic effect and structure of NiWMoS phases    

Catalytic hydrogenation of insoluble organic matter of CS/Acetone from coal over mesoporous HZSM-5 supported

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10,   Pages 1505-1513 doi: 10.1007/s11705-022-2164-0

Abstract: Four supported catalysts, nickel and ruthenium on a HZSM-5 support, were prepared by equal volume impregnationThe properties of catalysts were investigated by catalytic hydro-conversion of 2,2′-dinaphthyl ether

Keywords: HZSM-5     Ni-based catalyst     catalytic hydrogenation     coal     model compound    

Fischer-Tropsch synthesis by reduced graphene oxide nanosheets supported cobalt catalysts: Role of support

Hasan Oliaei Torshizi, Ali Nakhaei Pour, Ali Mohammadi, Yahya Zamani, Seyed Mehdi Kamali Shahri

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 2,   Pages 299-309 doi: 10.1007/s11705-020-1925-x

Abstract: In this paper, a series of cobalt catalysts supported on reduced graphene oxide (rGO) nanosheets withThe activity of the prepared catalysts is evaluated in the Fischer-Tropsch synthesis (FTS).The prepared catalysts were carefully characterized by nitrogen adsorption-desorption, hydrogen chemisorption

Keywords: cobalt catalyst     cobalt particle size     Fischer-Tropsch synthesis     reduced graphene oxide     supported catalyst    

Title Author Date Type Operation

A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

Cunyao Li, Wenlong Wang, Li Yan, Yunjie Ding

Journal Article

Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

Journal Article

Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Journal Article

Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

Journal Article

Catalytic combustion of volatile organic compounds using perovskite oxides catalysts—a review

Journal Article

Conversion of CO into CO by high active and stable PdNi nanoparticles supported on a metal-organic framework

Journal Article

Crystalline porous materials: from zeolites to metal-organic frameworks (MOFs)

Zaiku Xie, Bao-Lian Su

Journal Article

Electrochemical sensor investigation of carbon-supported PdCoAg multimetal catalysts using sugar-containing

Firat Salman, Hilal C. Kazici, Hilal Kivrak

Journal Article

Synthesis of porous carbon from orange peel waste for effective volatile organic compounds adsorption

Journal Article

Optimized porous clay heterostructure for removal of acetaldehyde and toluene from indoor air

Pu ZHAO,Lizhong ZHU

Journal Article

Computational design of heterogeneous catalysts and gas separation materials for advanced chemical processing

Huaiwei Shi, Teng Zhou

Journal Article

Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang, Zongbi Bao, Huabin Xing, Qilong Ren

Journal Article

Tuning of the active phase structure and hydrofining performance of alumina-supported tri-metallic WMoNicatalysts via phosphorus incorporation

Shufeng Shan, Haiyan Liu, Gang Shi, Xiaojun Bao

Journal Article

Catalytic hydrogenation of insoluble organic matter of CS/Acetone from coal over mesoporous HZSM-5 supported

Journal Article

Fischer-Tropsch synthesis by reduced graphene oxide nanosheets supported cobalt catalysts: Role of support

Hasan Oliaei Torshizi, Ali Nakhaei Pour, Ali Mohammadi, Yahya Zamani, Seyed Mehdi Kamali Shahri

Journal Article